PL EN
Turbidity-associated and warm-season manganese patterns at river and canal drinking-water intakes in Hai Phong City, Vietnam: statistical evidence and same-day alert rules from routine monitoring data
 
More details
Hide details
1
Faculty of Water Resources Engineering, Thuyloi University, 175 Tay Son Street, Kim Lien Ward, Hanoi 100000, Vietnam
 
 
Corresponding author
The Anh Nguyen   

Faculty of Water Resources Engineering, Thuyloi University, 175 Tay Son Street, Kim Lien Ward, Hanoi 100000, Vietnam
 
 
 
KEYWORDS
TOPICS
ABSTRACT
Manganese (Mn) often has to be removed at treatment plants that draw water from lowland rivers and canals, but particle-bound Mn and dissolved Mn(II) require different treatments, and only total concentrations are reported by routine monitoring. It was examined whether records already kept by utilities can separate turbidity-associated from warm-season Mn patterns and support daily raw-water decisions. Routine data (2021–2024; 3,451 Mn and 2,022 iron determinations) from seven intakes on four sources in Hai Phong City, Vietnam, were analyzed with fixed-effects, generalized additive, and segmented regressions and gradient-boosted trees. Total Mn exceeded 0.1 mg L−1 in 47.6% of samples (10.7% in February, 87.5% in September). Mn and iron (Fe) rose almost equally with turbidity, leaving the Mn/Fe ratio, on average, unchanged (standardized β = +0.004, 95% CI −0.017 to 0.023). The ratio increased instead with a 30-day water-temperature index (T30) marking the warm season (β = +0.036, 0.019 to 0.055) but not with temperature anomalies, so the pattern is seasonal rather than demonstrably temperature-driven. Above a transition zone near 25 °C, Mn rose 14.2% per °C of T30. Five routine variables reproduced Mn at withheld intakes, sources, and years (log-scale Nash–Sutcliffe efficiency 0.73–0.79, linear model). In leave-one-year-out tests, same-day alert rules combining a seasonal term with turbidity raised the critical success index by 0.08–0.09 over a fixed calendar. As only routine variables are needed, likely exceedance of the 0.1 mg L−1 limit can be flagged in a spreadsheet on the sampling day, before the laboratory Mn result is reported.
Journals System - logo
Scroll to top